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You can’t separate a printed film from photos you print from your computer (actually there is no film to separate – different technology). The computer ink will bleed when any liquid touches it. So be sure to use a commercially printed photo.
The special product you recall may not be available anymore; or, if it is, it might not work with today’s commercially printed photos. The technology has changed a lot.
The good news is that you can separate the plastic film from a photo using plain ol’ H2O. Read my Photo Finish article for how to separate the photo film and glue it to a smooth surface.
As for finishes which will offer the best protection outdoors, you will probably want to use a combination.
First of all, your photo plaque will be exposed to UV radiation. So I would start with two coats of
Krylon Spray UV-Resistant Clear gloss #1305
and finish with two coats of
Krylon Crystal Clear Universal Coating to protect it from the (other) elements.
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